Is it possible to create a PDF from a report in salesforce?

No creating a pdf from report is not possible as of right now. Maybe you can do is to create a VF page, embed the standard report in your page and use the renderAs=”pdf” attribute to achieve this.

Hi satyakam,

It won’t be possible using salesforce native report functionality.You can only export as CSV or Xls.There is a custom workaround, you can check this out:
http://salesforcesource.blogspot.com.br/2009/04/how-to-create-word-pdf-or-excel-files.html

Thanks