Why it is not possible to do Synchronous Web service callouts from scheduled apex in Salesforce?

Hi Prachi,

No, Synchronous Web service callouts are not supported from scheduled Apex. To be able to make callouts, make an asynchronous callout by placing the callout in a method annotated with @future(callout=true) and call this method from scheduled Apex. However, if your scheduled Apex executes a batch job, callouts are supported from the batch class.